Advice By Paul Gaines, Ph.D
Anita was hoping Paul could give her some general information on metals that are incompatible with each other within the same solution (for example, element A causes element B to drop out of solution).
I recommend you try using the Interactive Periodic Table. Click on any element of interest and look closely at the Chemical Compatibility data for that element. Additionally I encourage you to see our Sample Preparation Guide which includes highly detailed preparation chemistry for metals and many other elements.
The most common compatibility issues we encounter are as follows:
- Ag+ and trace Cl1-
- SO4= and Pb2+, Ba2+, Cr2O7=
- Rare Earth and Alkaline Earth elements mixed with the "fluoride" elements (Ti, Zr, Nb, Hf, Ta W, Si, Sn, Sb, Ge)
- "Fluoride" elements mixed with higher amounts of any transition elements, especially Sn and W
- Hg at concentrations below 10 ppm or mixed with elements containing organic ligands, such as Antimony Tartrate
- Antimony Tartrate in strong (≥ 5%) nitric acid
I hope this helps. I look forward to hearing from you if you need further assistance.
Serving you in chemistry,
Paul R. Gaines, Ph.D.
CEO of Inorganic Ventures
DISCLAIMER: Advice offered by the chemists at Inorganic Ventures is intended for the individual posing the question.
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