10,000ug/mL ZIRCONIUM 125mL

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SKU: CGZR10-125ML

10,000ug/mL ZIRCONIUM 125mL

Zirconium Expanded View

Zirconium

Location:  Group 4, Period 5
Atomic Weight:  91.224
Coordination Number:  6, 7, 8
Chemical Form in Solution:  Zr(F)6-2
(coordination numbers in green are observed less frequently)

Storage & Handling:  Keep tightly sealed when not in use. Store and use at 20 ± 4°C. Do not pipet from container. Do not return portions removed for pipetting to container.

Chemical Compatibility:  Soluble in concentrated HCl, HF, H2SO4 (very hot) and HNO3. Avoid H3PO4 and neutral to basic media. Unstable at ppm levels with metals that would pull F- away (i.e. - do not mix with Alkaline or Rare Earths or high levels of transition elements unless they are fluorinated). Stable with most inorganic anions but precipitation with phosphate, oxalate, and tartrate with a tendency to hydrolyze forming the hydrated oxide in all dilute acids except HF.

Stability:  2-100 ppb levels stable (alone or mixed with all other metals that are at comparable levels) as the Zr(F)6-2 + Zr(OH)4F2-2 for months in 1% HNO3 / LDPE container. 1-10,000 ppm single element solutions as the Zr(F)6-2 chemically stable for years in 2-5% HNO3 / trace HF in an LDPE container.

Zr Containing Samples (Preparation & Solution):  Metal (soluble in H2O / HF / HNO3); Oxide unlike TiO2, the ZrO2 is best fused in one of the following ways (Na2O2 in Ni0, Na2CO3 in Pt0 or Borax in Pt0); Organic Matrices (dry ash at 450&degC in Pt0 and dissolve by fusing with Na2CO3 and dissolving in HF / HNO3 / H2O).

Atomic Spectroscopic Information:  (red text indicates severe at ~ concs.)
Technique / Line Estimated D.L.* Order Type Interferences
ICP-OES 343.823 nm 0.007/.0004 µg/mL 1 ion Hf, Nb
ICP-OES 339.198 nm 0.008/.0007 µg/mL 1 ion Th, Mo
ICP-OES 272.261 nm 0.018/.001 µg/mL 1 ion Cr, V, Th, W
ICP-MS 90 amu 2 ppt n/a M+ 74Ge16O, 74Se16O,
[180X+2 (where X = Hf, Ta, W)]
*ICP-OES D.L.'s are given as radial / axial view

Zirconium (Zr) Standards In Our Store

Product Specifications

  • Part #:

    CGZR10-125ML

  • Description:

    10,000ug/mL ZIRCONIUM 125mL

  • Matrix:

    1.1% v/v Hydrofluoric Acid

  • Starting Material:

    ZrO2

Every Inorganic Ventures CRM is sold in patented TCT packaging giving your product up to 3 years shelf life. Read more...

 
    • Analyte
    • µg/mL
    • Zr
    • 10000
 
Documentation:
 

Associated Certifications: ISO 17034 | ISO 17025

 

Only Inorganic Ventures can give you ALL of these.....

Traceable to NIST SRMs
Produced under ISO 17025
Produced under ISO 17034
Assayed by validated wet chemical procedures
Assayed by validated ICP-OES procedures
Trace metallic impurities determined by ICP and ICP-MS

And up to 3 YEARS SHELF LIFE with TCT packaging