Lithium Expanded View

Lithium

Location:  Group 1, Period 2
Atomic Weight:  6.941
Coordination Number:  (6)
Chemical Form in Solution:  Li+(aq) (large effective radius due to hydration sphere)
(coordination number in parentheses is assumed, not certain)

Storage & Handling:  Keep tightly sealed when not in use. Store and use at 20 ± 4°C. Do not pipet from container. Do not return portions removed for pipetting to container.

Chemical Compatibility:  Soluble in HCl, HNO3, H2SO4, and HF aqueous matrices. Stable with all metals and inorganic anions.

Stability:  2-100 ppb levels stable for months in 1% HNO3 / LDPE container. 1-10,000 ppm solutions chemically stable for years in 1-5% HNO3 / LDPE container.

Li Containing Samples (Preparation & Solution):  Metal (dissolves very rapidly in water); Ores (sodium carbonate fusion in Pt0 followed by HCl dissolution - blank levels of Li in sodium carbonate critical); Organic Matrices (Sulphuric / peroxide digestion or nitric / Sulphuric / perchloric acid decomposition).

Atomic Spectroscopic Information:  (red text indicates severe at ~ concs.)
Technique / Line Estimated D.L.* Order Type Interferences
ICP-OES 670.784 nm 0.002/.00002 µg/mL 1 atom **
ICP-OES 460.286 nm 0.9/.04 µg/mL 1 atom Zr, Th
ICP-OES 323.261 nm 1.1/.05 µg/mL 1 atom Sb, Th, Ni
ICP-MS 7 amu 10 ppt n/a M+  
*ICP-OES D.L.'s are given as radial / axial view
**2nd order radiation from R.E.s on some optical designs

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