1000ug/mL ZIRCONIUM 500mL

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1000ug/mL ZIRCONIUM 500mL

Zirconium Expanded View


Location:  Group 4, Period 5
Atomic Weight:  91.224
Coordination Number:  6, 7, 8
Chemical Form in Solution:  Zr(F)6-2
(coordination numbers in green are observed less frequently)

Storage & Handling:  Keep tightly sealed when not in use. Store and use at 20 ± 4°C. Do not pipet from container. Do not return portions removed for pipetting to container.

Chemical Compatibility:  Soluble in concentrated HCl, HF, H2SO4 (very hot) and HNO3. Avoid H3PO4 and neutral to basic media. Unstable at ppm levels with metals that would pull F- away (i.e. - do not mix with Alkaline or Rare Earths or high levels of transition elements unless they are fluorinated). Stable with most inorganic anions but precipitation with phosphate, oxalate, and tartrate with a tendency to hydrolyze forming the hydrated oxide in all dilute acids except HF.

Stability:  2-100 ppb levels stable (alone or mixed with all other metals that are at comparable levels) as the Zr(F)6-2 + Zr(OH)4F2-2 for months in 1% HNO3 / LDPE container. 1-10,000 ppm single element solutions as the Zr(F)6-2 chemically stable for years in 2-5% HNO3 / trace HF in an LDPE container.

Zr Containing Samples (Preparation & Solution):  Metal (soluble in H2O / HF / HNO3); Oxide unlike TiO2, the ZrO2 is best fused in one of the following ways (Na2O2 in Ni0, Na2CO3 in Pt0 or Borax in Pt0); Organic Matrices (dry ash at 450&degC in Pt0 and dissolve by fusing with Na2CO3 and dissolving in HF / HNO3 / H2O).

Atomic Spectroscopic Information:  (red text indicates severe at ~ concs.)
Technique / Line Estimated D.L.* Order Type Interferences
ICP-OES 343.823 nm 0.007/.0004 µg/mL 1 ion Hf, Nb
ICP-OES 339.198 nm 0.008/.0007 µg/mL 1 ion Th, Mo
ICP-OES 272.261 nm 0.018/.001 µg/mL 1 ion Cr, V, Th, W
ICP-MS 90 amu 2 ppt n/a M+ 74Ge16O, 74Se16O,
[180X+2 (where X = Hf, Ta, W)]
*ICP-OES D.L.'s are given as radial / axial view

Zirconium (Zr) Standards In Our Store

Product Specifications

  • Part #:


  • Description:

    1000ug/mL ZIRCONIUM 500mL

  • Matrix:

    tr Hydrofluoric Acid

  • Starting Material:


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Traceable to NIST SRMs
Produced under ISO 17025
Assayed by validated wet chemical procedures
Assayed by validated ICP-OES procedures

And up to 3 YEARS SHELF LIFE with TCT packaging